Graphene oxide is not a good conductor, but processes exist to augment its properties. Preparation and characterization of graphene oxide paper. Synthesis of graphene oxide go by modified hummers method. Nanomaterials free fulltext effect of graphene oxide. Graphene is a carbon based material that can be viewed as a one atom thick sheet of graphite and has been investigated intensely in recent years following a report by novoselov et al. Using suitable choice of reaction parameters including temperature and time, this recipe does not. Highquality graphene via microwave reduction of solution. Go plays important roles in the sustainable development of energy and the environment, taking advantages of oxygencontaining functional groups for good dispersibility and assembly. During the oxidation process, graphite crystal was treated with strong oxidizing.
These results are in near concord with results reported earlier graphene at different diffraction peaks varies from 32 to 84 nm as calculated from scherrers formula. The drivers for these advancements are the ease of. Comprehensive characterizations of the properties of go films were conducted. Morphology is discussed through optical microscopy, fluorescence. Reduced graphene oxide an overview sciencedirect topics.
An energetic composite material based on graphene oxide and ammonium perchlorate was prepared using a recrystallization method involving acetone and ethyl acetate as the solvent and antisolvent, respectively. Graphene oxide as a substrate for a variety of chemical transformations, including its reduction to graphene like materials, is also discussed. The strong absorption band at 1034 cm1 hydroxyapatite and hydroxyapatitegraphene oxide confirms the stretching vibration of po4 while the bending composite. In recent years, graphene oxide has attracted great concern mainly because it is a potential starting material for the mass production of graphene. Tem and dfm analyses showed that go sheets prepared in this study had single and double lamellar layer.
Ncs with molecular recognition ability for bioimaging currently remains a challenge. Tricalcium silicategraphene oxide bone cement with. Todays graphene is normally produced using mechanical or thermal exfoliation, chemical vapour deposition cvd, and epitaxial growth. Since the upper size limit is predetermined by the diameter of the nanofiber precursor, the size distribution of the go nanosheets is much more uniform than that. Facile assembly of 3d porous reduced graphene oxideultrathin. Compared with hummers method, electrochemical exfoliation of graphite is considered facile and. This method resulted in the production of small crystals, where the graphene oxide wraps around the ammonium perchlorate particle to form a composite particle. The maximally oxidized bulk product is a yellow solid with c. Journal of materials chemistry b tricalcium silicategraphene oxide bone cement with photothermal properties for tumor ablation chen xu, a bing ma, a jinliang peng, b long gao, a yuhong xu, b zhiguang huan a and jiang chang a. Reduced graphene oxide rgo was thereafter extracted by thermal modifica tion of go.
Due to its unique properties, graphene oxide has become one of the most studied materials of the last decade and a great variety of applications have been reported in areas such as sensors, catalysis and biomedical applications. This paper evaluated the effect of graphene oxidegraphene gogr hybrid on mechanical properties of cement mortar. Jul 26, 2007 here we report the preparation and characterization of graphene oxide paper, a freestanding carbonbased membrane material made by flowdirected assembly of individual graphene oxide sheets. These are some examples of our recent publications.
Review article graphene and graphene oxide composites and. This study develops a new type of tricalcium silicate cs based functional bone cement with excellent photothermal performance. Graphene can be synthesized by chemical vapor deposition e. The membranes are typically obtained by slow evaporation of graphene oxide solution or by the filtration.
Graphite oxide, formerly called graphitic oxide or graphitic acid, is a compound of carbon, oxygen, and hydrogen in variable ratios, obtained by treating graphite with strong oxidizers. Incorporating polymer into graphene oxide and gra phene buckypaper may modify the polymer and filler properties producing high performance materials. Graphene oxide is an oxidized form of graphene, laced with oxygencontaining groups. Responsive fluorescence enhancement in graphene oxide. In this porous network architecture, rgo serves as an electron and ion transfer pathway, a physical adsorption site for.
During the reaction, graphene oxide sheets are reduced and self. The preparation of composite material of graphene oxide. This comprehensive volume systematically describes the fundamental aspects and applications of graphene oxide. Due to the presence of oxygen functionalities, graphene oxide can easily disperse in.
Reduced graphene oxide rgo is the form of go that is processed by chemical, thermal and other methods in order to reduce the oxygen content, while graphite oxide is a material produced by oxidation of graphite which leads to increased interlayer spacing and functionalization of the basal planes of graphite. Graphene oxide paper or graphite oxide paper is a material fabricated from graphite oxide. Currently, hummers method kmno4, nano3, h2so4 is the most common method used for preparing graphene oxide. Reduced graphene oxide modified activated carbon for improving power generation of aircathode microbial fuel cells volume 33 issue 9 yang yang, tianyu liu, hanyu wang, xun zhu, dingding ye, qiang liao, ke liu, shaowei chen, yat li. The surface of graphene oxide contains epoxy, hydroxyl, and carboxyl groups, which can interact with cations and anions. Conference series paper open access chitosangraphene oxide biocomposite film from pencil rod.
Discussion and references for further research on graphene are provided. Graphene oxide nanocolloids journal of the american. Pdf structure and synthesis of graphene oxide researchgate. Efficient exfoliation of graphite in solutions to obtain highquality graphene flakes is desirable for printable electronics, catalysis, energy storage, and composites. In this study, we investigated the directional heating of graphene oxide go dispersion to generate a temperature gradient and form a simulated ocean current inside the dispersion so that go sheets could be aligned in a directional manner and then reduced and selfassembled into anisotropic reduced graphene oxide rgo gel. Subsequently reduced graphene oxide rgo having few layer graphene is extracted from go by the thermal reduction of go. Probing the mechanical properties of verticallystacked ultrathin graphene al2o3 heterostructures nanotechnology19 february 2019 electrochemically active ir nps on graphene for oer. An improved method for the preparation of graphene oxide go is described. Because the oxygenated functional groups in graphene oxide go. Here we propose a strategy of radical oxidation reaction for the highefficiency production of graphene oxide go. Synthesis of graphene oxide scientific research publishing. International journal of engineering trends and technology ijett. Their unique properties are not only restricted to graphene but also shared with derivative compounds like graphene oxide, reduced graphene oxide, functionalized graphene, and so forth.
Pdf graphene oxide go can be regarded as one typical twodimension structured oxygenated. Graphene oxideammonium perchlorate composite material for. Biofabrication of lysinibacillus sphaericusreduced graphene oxide in threedimensional polyacrylamidecarbon nanocomposite hydrogels for. This element is unique in that its unique electronic structure allows for hybridization to build up sp3,sp2, and sp networks and, hence, to form more known stable allotropes than any. Synthesis, properties, and applications of graphene oxidereduced. In addition, the effect of the distribution of go and rgo nanoparticles in epoxy matrix on the corrosion performance. Preparation and characterization of graphene oxide hindawi. Micrometer thick films of graphene oxide paper are also named as graphite oxide membranes in the 1960s or more recently graphene oxide membranes. He spent five years at rice university studying fundamental aspects of graphene oxide, resulting in several groundbreaking papers in highly ranked journals including nature and science, followed by a period at az electronic materials where he worked on optimizing mass production of graphene oxide, and on developing novel graphene oxide. The composites showed high specific capacitance and good cycling stability, thus they are proved to be promising cathode materials for supercapacitors. Photosynergetic electrochemical synthesis of graphene oxide. The graphene oxide has proven to be soluble in water, is amphiphilic, nontoxic and biodegradable and form stable colloids.
Although graphite oxide is a multilayer system, monolayer flakes and fewlayer flakes can be found in a graphene oxide dispersion. It is considered easy to process since it is dispersible in water and other solvents, and it can even be used to make graphene. The journal carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials and carbon nanomaterials. The book is designed as an introduction to the topic, so. Special issue synthesis and applications of graphite oxide. Graphene has received so much attention due to its exceptional electronic, thermal, mechanical, and optical properties in addition to its large surface area and singleatom thickness. This yields a material with a significant number of oxygencontaining functional groups which assures homogeneous colloidal suspensions in polar solvents without addition of any surfactant. Sigmaaldrich offers a number of graphene oxide products.
The interlayer distance in diluted naoh reached infinity, resulting in dispersion of graphite oxide on singlelayered graphene oxide sheets in solution. Graphene and graphene oxide carbon nanomaterials sigma. Journal of materials chemistry a 3d superhydrophobic reduced graphene oxide for activated no 2 sensing with enhanced immunity to humidity jin wu, a zhong li, b xi xie, a kai tao, c chuan liu, a khiam aik khor, b jianmin miao b and leslie k. For the mortar specimen, flexural and compressive strength were measured at. Since the first report on mechanical exfoliation of monolayer graphene in 2004, interest in graphite oxide which is produced by. Graphene oxide metal oxide mixed nanocomposites have attracted extensive attention in recent days because of the large surface area of graphene moiety which offers sufficient space to accommodate different nanomaterials preventing agglomeration of.
Synthesis of graphene oxide go by modified hummers. It is proven that redox method is a promising way to synthesize go films on a large scale. A low cost, nonexplosive process for the synthesis of graphene oxide go is demonstrated. At an appropriate concentration, evaporation of droplets of such a colloidal suspension on a surface. The synthesis, properties, and applications of graphene and graphene oxide. Because of their simple topdown synthesis, graphene oxide go and reduced. Preparation and characterization of graphene oxide paper nature. Particular emphasis is directed toward the synthesis of graphene oxide, as well as its structure.
Aug, 2019 in this study, the effect of graphene oxide go and reduced graphene oxide rgo nanoparticles on the corrosion protection performance of nanocomposite coatings containing particle mass concentration ranging from 0. In the gogr hybrid, go was expected to act as a dispersant for gr while gr was used as reinforcement in mortar due to its excellent mechanical properties. The preparation of graphene oxide and its derivatives and their. Graphene oxidemetal oxide mixed nanocomposites have attracted extensive attention in recent days because of the large surface area of graphene moiety which offers sufficient space to accommodate different nanomaterials preventing agglomeration of. Graphene oxide go films with twodimensional structure were successfully prepared via the modified hummer method. Graphite oxide with large lateral dimensions has an exfoliation yield of 100%, but it has not been possible to completely remove the oxygen functional groups so that the reduced form of graphene oxide go. Characterization of structural transformation of graphene oxide to reduced graphene oxide during thermal annealing.
One of the most structurally important materials, graphene oxide go, is prepared by the. However, traditional bone cements do not have the function to kill tumor cells. Rheological properties and anticorrosion performance of. Recently, graphene and other graphenebased materials have become an essential part of composite science and technology. Graphene oxide is a singlelayer sheet of graphite oxide, which was proposed one and a half century ago. Polyurethane nanocomposites containing reduced graphene. By a simple solvothermal reaction process, nanosized s atoms are homogeneously decorated into the 3d scaffold formed by reduced graphene oxide rgo and mno 2 nanosheets, which can form the homogeneous rgm. The lattice expansion becomes stronger at lower temperatures. Oct, 2015 many exciting developments on neat graphene and graphene oxide go fibres have been reported by research groups worldwide 1,2,3,4,5,6,7,8,9.
The surface of graphene oxide contains epoxy, hydroxyl, and carboxyl groups, which. However, very little is known regarding the chemically induced reduction method of graphene oxide go in both solution. Pdf synthesis, properties of graphene oxidemetal oxide. Graphene oxide has been prepared by a modification of the hummers method. In this study, the effect of graphene oxide go and reduced graphene oxide rgo nanoparticles on the corrosion protection performance of nanocomposite coatings containing particle mass concentration ranging from 0. Review article graphene and graphene oxide composites and their electrorheological applications wenlingzhang, 1,2 jingquanliu, 1 andhyoungjinchoi 2 college of chemical science and engineering, qingdao university, qingdao, china. Facile assembly of 3d porous reduced graphene oxide. Natural flake graphite nfg was procured from loba chemie india having a mean size of 60 mesh and purity of 98%. Bone cements have been used in the clinical setting to fill bone defects resulting from bone tumors. Threedimensional, superhydrophobic, reduced graphene oxide rgo with unique hierarchical structures is synthesized by spark plasma sintering sps in one step for highly selective no2 detection. Graphene oxide as a substrate for a variety of chemical transformations, including its reduction to graphenelike materials, is also discussed.
Reduced graphene oxides rgos have attracted considerable interest, given their potential applications in electronic and optoelectronic devices and circuits. In addition, the effect of the distribution of go and rgo nanoparticles in epoxy matrix on the corrosion performance and. Synthesis and fabrication of graphene and graphene oxide. Graphene oxide go has been initially prepared by a modified hummersmethod. Here we report the preparation and characterization of graphene oxide paper, a freestanding carbonbased membrane material made by flow. Graphite oxide can be used as a cation exchange membrane for materials such as kcl, hcl, cacl2, mgcl2, bacl2 solutions. Application note graphene and graphene oxide material that can be exfoliated to form stable colloidal suspensions in water. Pdf synthesis and characterization of hydroxyapatite. The field of nanotechnology has advanced following the discovery of a twodimensional material of sp2 hybridized carbon atoms, graphene in 2004 by geim and novoselov. One of the most effective way of synthesised graphene on a large scale could be by the chemical reduction of graphene oxide. Many exciting developments on neat graphene and graphene oxide go fibres have been reported by research groups worldwide 1,2,3,4,5,6,7,8,9. This paper evaluated the effect of graphene oxide graphene gogr hybrid on mechanical properties of cement mortar.
Recently, graphene and other graphene based materials have become an essential part of composite science and technology. Probing the mechanical properties of verticallystacked ultrathin grapheneal2o3 heterostructures nanotechnology19 february 2019 electrochemically active ir nps on graphene for. Graphene oxide go nanocolloidssheets with lateral dimension smaller than 100 nmwere synthesized by chemical exfoliation of graphite nanofibers, in which the graphene planes are coinstacked along the length of the nanofibers. Polyurethane nanocomposites containing reduced graphene oxide. Due to the presence of oxygen functionalities, graphene oxide can easily disperse in organic solvents, water, and different matrixes. The journal reports new, relevant and significant findings related to the formation, structure, properties, behaviors, and technological applications of carbons, which are a broad class.
1397 692 1356 318 295 351 1512 1125 1169 935 948 1126 289 201 804 1379 381 1573 71 882 661 108 640 1463 423 1411 921 1216 1190 922 516 562 1087 1505 196 359 975 1347 1425 91 1428 588 738 305